Material Safety Data Sheet - (Permanent Marker INK)

SECTION 3 HAZARD IDENTIFICATION 

Classified as Hazardous according to criteria of Reach 

Substance name : [Ethyl alcohol] 

Classification:F; R11 

R-Phrase: R11Highly flammable. 

S-Phrase: S2 Keep out of the reach of children. 

 S7Keep container tightly closed. 

 S16Keep away from sources of ignition - No smoking. 

Symbols and indications of danger specific F : Highly flammable 

Substance name : [1-methoxypropan-2-ol ] 

Classification:R10 - R67 

R-Phrase: R10 Flammable. 

 R67 Vapours may cause drowsiness and dizziness. 

S-Phrase: S2 Keep out of the reach of children. 

Symbols and indications of danger specificnone 

Product definition : Mixture 

See Section 16 for the full text of the R phrases or H statements declared above. Classification according to Directive 1999/45/EC [DPD] 

The product is classified as dangerous according to Directive 1999/45/EC and its amendments. Classification : R10 

Physical/chemical hazards : Flammable. 

Potential Health Effects 

Eye: Causes severe eye irritation. May cause painful sensitization to light. May cause chemical  conjunctivitis and corneal damage. 

Skin: Causes moderate skin irritation. May cause cyanosis of the extremities. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause  systemic toxicity with acidosis. May cause central nervous system depression, characterized by  excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may  cause collapse, unconsciousness, coma and possible death due to respiratory failure. Inhalation: Inhalation of high concentrations may cause central nervous system effects  characterized by nausea, headache, dizziness, unconsciousness and coma. Causes respiratory  tract irritation. May cause narcotic effects in high concentration. Vapors may cause dizziness or  suffocation. 

Chronic: May cause reproductive and fetal effects. Laboratory experiments have resulted in  mutagenic effects. Animal studies have reported the development of tumors. Prolonged exposure  may cause liver, kidney, and heart damage. 

SECTION 4 FIRST AID MEASURES

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the  upper and lower eyelids. Get medical aid. Gently lift eyelids and flush continuously with water. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing  contaminated clothing andshoes. Wash clothing before reuse. Flush skin with plenty of soap and  water. 

Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or  water. Never give anything by mouth to an unconscious person. Get medical aid. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give  artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use  mouth-to-mouth resuscitation. breathing is difficult, give oxygen. Get medical aid. Do NOT use  mouth-to-mouth resuscitation. 

Notes to Physician: Treat symptomatically and supportively. Persons with skin or eye disorders or  liver, kidney, chronic respiratory diseases, or central and peripheral nervous sytem diseases may  be at increased risk from exposure to this substance. 

SECTION 5 FIRE FIGHTING MEASURES 

General Information: Containers can build up pressure if exposed to heat and/or fire. As in any  fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or  equivalent), and full protective gear. Vapors may form an explosive mixture with air. Vapors can  travel to a source of ignition and flash back. Will burn if involved in a fire. Flammable Liquid. Can  release vapors that form explosive mixtures at temperatures above the flashpoint. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. 

Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or  alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water  spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of  water. 

Flash Point: 16.6 deg C ( 61.88 deg F) 

Autoignition Temperature: 363 deg C ( 685.40 deg F) 

Explosion Limits, Lower:3.3 vol % 

Upper: 19.0 vol % 

NFPA Rating: (estimated) Health: 2; Flammability: 3; Instability: 0 

SECTION 6 ACCIDENTAL RELEASE MEASURES 

Steps to be Taken if Material is Released or Spilled: Small spills: Absorb with materials such as: Sand. Vermiculite. Collect in suitable and properly labeled containers. Large spills: Contain spilled material if possible. Ground and bond all containers and handling equipment. Pump with  explosionproof equipment. If available, use foam to smother or suppress. See Section 13,  Disposal Considerations, for additional information. 

Personal Precautions: Isolate area. Refer to Section 7, Handling, for additional precautionary measures. Keep unnecessary and unprotected personnel from entering the area. Keep personnel  out of low areas. Keep upwind of spill. Ventilate area of leak or spill. No smoking in area.  Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion.  Vapor explosion hazard. Keep out of sewers. For large spills, warn public of downwind explosion 

hazard. Check area with combustible gas detector before reentering area. Ground and bond all  containers and handling equipment. Eliminate all sources of ignition in vicinity of spill or released  vapor to avoid fire or explosion. Ground and bond all containers and handling equipment. Use  appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls  and Personal Protection. 

Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. 

SECTION 7 STORAGE AND HANDLING 

Storage Temperature: ≤30℃ 

Shelf Life: one year 

Special Sensitivity: No available information 

Handling and Storage: 

Handling: Wash thoroughly after handling. Use only in a well-ventilated area. Ground and bond  containers when transferring material. Use spark-proof tools and explosion proof equipment.  Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid  and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat,  sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill,  grind, or expose empty containers to heat, sparks or open flames. 

Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a  tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry,  well-ventilated area away from incompatible substances. Flammables-area. Do not store near  perchlorates, peroxides, chromic acid or nitric acid. 

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION 

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's  eye and face， protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. 

Clothing: Wear appropriate protective clothing to prevent skin exposure. 

Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI  Z88.2 requirements or European Standard EN 149 must be followed whenever workplace  conditions warrant a respirator's use. 

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES 

Physical Form: liquid Color: - 

Odor: alcohol Flash Point: 25℃ 

Boiling Point:>78℃ Melting Point: - 

Freezing Point: Not Applicable PH:4-8 

Solubility in Water: 100% Specific Gravity: -

Bulk Density: - Volatile by Weight:- Vapour Pressure: 59.3mmHG Vapour Density:- 

SECTION 10 STABILITY AND REACTIVITY 

Stability/Instability 

Thermally stable at typical use temperatures. 

Conditions to Avoid: Do not distill to dryness. Product can oxidize at elevated temperatures. Generation of gas during decomposition can cause pressure in closed systems. Incompatible Materials: Avoid contact with: Strong acids. Strong bases. Strong oxidizers. Hazardous Polymerization 

Will not occur. 

Thermal Decomposition 

Decomposition products depend upon temperature, air supply and the presence of other materials.) SECTION 11 TOXICOLOGICAL INFORMATION 

AcuteToxicity(ethanol): 

Oral-rat LD50 >5,000 mg/kg 

Inhalation-rat LC50 >20 mg/L/4h 

Oral-rat LD50 >2,000 - <=5,000 mg/kg 

Dermal-rabbit LD50 >5,000mg/kg 

Inhalation-rat LC50 >20 mg/L/4h 

Eyes Causes irritation to the eyes. Can cause painful sensitization to light. Can cause a form of  chemicalconjunctivitis and cause corneal damage. 

Ingestion Can cause gastrointestinal irritation with nausea, vomiting and diarrhea. Systemic  toxicity and acidosis can occur. Advanced stages can lead to respiratory failure, kidney failure,  coma, and death. 

Inhalation Causes respiratory tract irritation. Can cause narcotic effects in high concentration.  Vapors may cause dizziness or suffocation. Systemic toxicity and acidosis can occur. Advanced  stages can lead to respiratory failure, kidney failure, coma, and death. 

Skin Causes moderate skin. Can cause dermatitis by de-fatting the skin from prolonged or  repeated contact. 

SECTION 12 ECOLOGICAL INFORMATION 

NO ECOLOGICAL ISSUES LIKELY.  

SECTION 13 DISPOSAL CONSIDERATION 

Description of waste residues and information on their safe handling and methods of disposal,  including the disposal of any contaminated packaging: 

Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in  igniting as this material is highly flammable. Observe all federal, state, and local environmental 

regulations. Contact a licensed professional waste disposal service to dispose of this material. SECTION 14 TRANSPORT INFORMATION 

UN number: 1170 

UN proper shipping name: Ethanol Solutions 

Transport hazard class(es) : 3 

Packing group (if applicable) II 

IMDG 

UN-Number: 1170 Class: 3 Packing Group: II 

EMS-No: F-E, S-D 

Proper shipping name: Ethanol Solutions 

Marine pollutant: No 

IATA 

UN-Number: 1170 Class: 3 Packing Group: II 

Proper shipping name: Ethanol Solutions 

SECTION 15 REGULATORY INFORMATION 

Safety, health and environmental regulations specific for the product in question: OSHA Hazards: Flammable liquid, Target Organ Effect, Irritant All ingredients are on the following inventories or are exempted from listing Country Notification 

Australia AICS 

Canada DSL 

China IECS 

European Union EINECS 

Japan ENCS/ISHL 

Korea ECL 

New Zealand NZIoC 

Philippines PICCS 

United States of America TSCA 

SECTION 16 OTHER INFORMATION 

Please consult the relevant product and/or application information for this product.